Advances in Inorganic Chemistry, Vol. 55 by Rudi van Eldik

By Rudi van Eldik

Advances in Inorganic Chemistry offers well timed and informative summaries of the present development in quite a few topic parts inside of inorganic chemistry starting from bio-inorganic to good nation reports. Thisacclaimed serial gains reports written through specialists within the zone and is an vital connection with complex researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is absolutely referenced. . accomplished studies written via major specialists within the box . An necessary connection with complicated researchers . comprises 7 contributions masking vital advances in inorganic chemistry

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Blackman, A. ; Tolman, W. B. Struct. Bonding (Berlin) 2000, 97 (Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations), 179^211. 21. Holland, P. ; Tolman, W. B. Coord. Chem. Rev. 1999, 190^192, 855^869. 22. Karlin, K. ; Zuberbuhler, A. D. Formation, structure, and reactivity of copper dioxygen complexes, ‘‘Bioinorganic Catalysis’’, 2nd edn. (Revised and Expanded); Eds. ; Marcel Dekker: New York, 1999, pp. 469^534. 23. ; Imahori, H. Biomimetic electron-transfer chemistry of porphyrins and metalloporphyrins, ‘‘Electron Transfer in Chemistry’’, Vol.

The reaction mechanism was probed by carrying out the oxidation of PhCH2OH in competition with several other alcohols, whose rate constants for the reaction with CraqO2 þ are independently known. If, as predicted, the kinetics are determined by the rate of disproportionation of HNO2, and CraqO2 þ is the active oxidant, then the added alcohols should have no e¡ect on the kinetics, but the yield of PhCHO should decrease by a predictable percentage as the oxidation products of competing alcohols grow in.

47). As one would expect, the kinetic nucleophilicity of HNO2 is less, but not in¢nitely less, than that of NOÀ 2. The reaction between HNO2 and L2(H2O)RhOO2 þ generated the nitrato intermediate, L2(H2O)Rh(NO3)2 þ , but the yield was only half of that observed earlier in the NO/L2(H2O)RhOO2 þ reaction. ATOM TRANSFER AND FREE RADICAL CHEMISTRY 41 SCHEME 12. The reduced yield is consistent with the proposal in Scheme 12, according to which only 50% of L2(H2O)RhOO2 þ reacts with NO, the other 50% being consumed by NO2, Eqs.

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